Bond breakage under pressure in a metal organic framework† †Electronic supplementary information (ESI) available: PXRD, SEM, FT-IR, fitting results of R-space EXAFS of UiO-66 nanocrystals. See DOI: 10.1039/c7sc03786d

Postsynthetic ionization of an imidazole-containing metal–organic framework for the cycloaddition of carbon dioxide and epoxides† †Electronic supplementary information (ESI) available: General comments, syntheses and characterizations of the MOFs mentioned in the manuscript, details of the single crystal diffraction experiments, PXRD, TG and additional figures. CCDC 1499016. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04357g Click here for additional data file. Click here for additional data file.

1. General experiments 2-(imidazol-1-yl)terephthalic acid (Im-H 2 BDC • HCl) was prepared by a similar process according to the literature. 1 Other reagents were purchased from commercial sources and used as received. N 2 and CO 2 sorption isotherms of Im-UiO-66 (1) and (I-)Meim-UiO-66 (2) were measured by using a Micrometrics ASAP 2420 instrument at 77 K and 273K, 298 K, respectively. Before t...

Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide†

4444 | Catal. Sci. Technol., 2015, 5, 4444–4451 This journal is © The R Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA. E-mail: [email protected] Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 22254, Saudi Arabia † Electronic supplementary information (...

Enhancing the stability and porosity of penetrated metal–organic frameworks through the insertion of coordination sites† †Electronic supplementary information (ESI) available: Experimental section, crystallographic tables, IR, TG and characterization details. CCDC 1576271 and 1576272. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04192f

State Key Laboratory of Elemento-Orga Collaborative Innovation Center of Chem Nankai University, Tianjin 300071, China. 22-23502458 School of Materials Science and Engine Materials, Tianjin Key Laboratory of Metal Nankai University, Tianjin 300350, China † Electronic supplementary information crystallographic tables, IR, TG and chara 1576272. For ESI and crystallographic dat DOI: 10.1039/c7sc04...

Photoinduced water oxidation by an organic ligand incorporated into the framework of a stable metal–organic framework† †Electronic supplementary information (ESI) available: Additional structure figures, TGA curve, adsorption isotherms, UV-vis spectra, ESR spectra, GC spectra, PXRD patterns, and an additional cyclic voltammogram. CCDC 1003764. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc02679b Click here for additional data file. Click here for additional data file.

Topochemical conversion of a dense metal–organic framework from a crystalline insulator to an amorphous semiconductor† †Electronic supplementary information (ESI) available: PXRD, impedance, TGA, IR, XPS, PDF, ESR, and CIF files. CCDC 1018776–1018778. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc03295k Click here for additional data file.

Department of Materials Science and Meta Babbage Road, Cambridge CB3 0FS, UK. 1223 334567; Tel: +44 (0) 1223 767061 International Center for Materials Nan Institute for Materials Science (NIMS), 1-1 N [email protected]; Tel: +81 2 Waseda Institute for Advanced Study (W Shinjuku, Tokyo 169-8555, Japan Department of Chemistry, University of O South Parks Road, Oxford, OX1 3QR, UK † Elec...